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Jul 18,  · 4-Vinylguaiacol is an important constituent in distilled spirits (whiskey, rum) where it contributes to the overall sweet smoky background notes. It also contributes to the flavour of Tobacco. Used in Coffee, Chocolate, Spice, Vanilla, Tea, Whiskey, Rum, Tobacco, Roasted Peanut and Strawberry flavors. Also used in Artificial Smoke flavors.